"Print through" residue left on mold surface after demold.


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seense
seense
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Hi!

When molding carbon parts with high Vf (>50%) the fibres touching the mold are leaving a residue on my mold surface. I don't know why this is happening. I just bought easy lease release agent, but it also happened with wax (Partall). In fact I thought the Partall wax had aged so I bought Easy Lease thanks to this forum. But unfortunately no difference. The parts are demolding easy though with easy lease.

I have been using different curing processes: 24h room temp, 48h room temp, 24h 30 degrees C, 48h 30 degrees C. All with the same outcome: a residue on the mold. The molds are machined of PU toolingboard (Renshape) and polished to a mirror surface. Epoxies used are L + GL2 / S / L and EPH161 from R&G. When making a hand layup of one ply of carbon without compaction there is no printthrough and also no residue on the mold surface after demolding just like when using a gelcoat prior to the lay up.  So it looks like the problem is related to the compaction of the fibre or it maybe an epoxy problem.

In the video of the small bonnet Easycomposites doesn't use a gelcoat either. Is there also a residue left on the mold? Or is this problem related to the used epoxy? I don't mind a little print through on the part but the problem is that I have to repolish the mold and re apply the easy lease which eliminates the advantage of a semi perm.


Warren (Staff)
Warren (Staff)
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My initial thoughts are it might well be a problem with the surface of the board in combination with the additional compression under vacuum.  This is assuming your cure cycles are fine for the resin system you have (not being familiar with your resin I cant be 100% sure but the times look realistic for curing for most epoxies). Most modeling boards are to an extent porous dependent on density. The higher the density, the more solid they are. It could be you are on the borderline with that PU board such that you get away fine under hand lay but the vacuum pressure is just enough to cause issues. 

Warren Penalver
Easy Composites / Carbon Mods - Technical Support Assistant
seense
seense
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Thanks for your reply. It's renshape 5173 (1200 kg/m3). The supplier told me that this type doesn't have to be sealed, and I thought Easy Lease doesn't need a sealer anyway?
Edited 8 Years Ago by seense
Matt (Staff)
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Unfortunately it's difficult for us to comment on what might be causing this issue because we don't know the behaviour of the resin or the board. As you've indicated, the Easy-Lease is releasing fine so the aspect that we know well does seem to be working correctly.

In the video that you've linked to, the surface of that mould is our Epoxy Tooling Gelcoat. The resin we're using is our IN2 Epoxy Infusion Resin and I can say for certain that this combination, with the Easy-Lease release agent did not and would not leave any residue on the mould surface. Mould is left perfectly clean and shiny and the part has a pristine finish.

To explain your problem, one possibility to consider is the fact that polyurethane boards, when used at elevated temperature, actually inhibit the cure of epoxy resin. This is a well-known phenomenon within composites circles dealing with prepregs where it's known that polyurethane board cannot be used as a tooling board for prepregs because the resin in contact with the board won't cure. In these situations, epoxy tooling board is required (which does not cause the same cure inhibition). It occurs to me that because you're using the board at elevated temperure and you're using epoxy reisn and you're not using a sealer (which might have helped to separate the board from the epoxy) you just might be experiencing this issue.

I hope this helps, Matt

Matt Statham
Easy Composites / Carbon Mods - Technical Sales
seense
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Thanks for pointing me in that direction and good to know you didn't have the problem in the video. I'll contact the supplier and post the outcome.
Edited 8 Years Ago by seense
seense
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Adding a little heat isn't the problem i guess since the problem also occurs when curing at room temp for 2 days. I also want to point out that I'm not using resin infusion, but RTM (two A sides), so maybe the compression force from the fibre on the mold is a bit higher due to the higher vf.

I contacted several suppliers for a solution. Only 1 replied so far and says the problem is most likely due to the absence of a sealer (micro porosity). Unfortunately not willing or not able to tell if their TR sealer is compatible with the easy lease and only promoting their own release systems.

In the meantime I read on the forum that release properties can differ when applying more coats of Easy Lease. So I took that to the test and applied 12 coats of easy lease. There was a noticeable difference between 12 or 6 coats when doing the tape test and releasing the part. Only a few spots on the mold. I'm not going to repolish the mold this time (the few leftovers I could remove with my nails) but will apply more coats of EL. Hoping the release gets better and better.

Is sealing capability of a single sealer superior to the sealing capability of EL?
I'm also wondering if I want to use a sealer can I use Marbocote sealer with EL? I read on the web that EL is most likely Marbocote 227CE in a different tin. Don't know if this is true, but would love to hear if Marbocote sealer is compatible with EL.
Hanaldo
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I'm a bit hesitant to post because I don't know if this will help or hinder you, but I'll share my experience and you can decide if it helps you. 

I have tried numerous brands and types of release agents with the Marbocote tool sealer, from Marbocote to Frekote to Zyvax Flex-Z to Zyvax Enviroshield. All if them worked perfectly, no issues whatsoever. I can't say that Easylease would be the same, however knowing how chemical release agents work leads me to believe that it would be fine. 

That said, I am somewhat in doubt that the lack of a sealer is your issue. For one, Easylease is supposed to be a 1-part system that includes a sealer. So whilst the application of a separate sealer shouldn't hinder the performance, I'm somewhat sceptical that it would actually aid it much if at all. And secondly, I have used all the aforementioned release agents with and without sealer. The Zyvax Flex-Z is more like the Easylease in that is has an inbuilt sealer, but the Frekote and the Marbocote are supposed to be used in combination with a sealer. There is no difference in release between the Frekote/Marbocote with or without a sealer. It releases just fine without the sealer, and it release just fine with the sealer. The only difference I have noticed is that it extends the life of the film. So instead of the 5 or 6 easy pulls that I will get without a sealer, I will get 9 or 10 easy pulls from the mould if I apply the sealer first. That's the only difference I can notice, everything else is exactly the same. 
seense
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Thanks! Appreciating every input and experience. Semi perms and RTM are new to me. After the last test I am also doubting if a lack of sealer is the problem. Maybe it's just about film thickness/strenght for this type of process. Although I thought one would have to apply multiple coats to ensure complete coverage. Or I don't understand how a semi perm works.

After demolding the last part I also noticed tape is sticking pretty bad again. So I guess I have to add multiple EL coats again. Wondering where all that release agent went because the part came out clean.
Hanaldo
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My gut feeling is that the issue will be chemical, like Matt was alluding to. I have had similar issues before when working with vinyl ester infusion resin, though because it was virtually a one off I never thought too much about the cause. 

I really think the issue is more likely to be a reaction between your mould surface and your resin system, rather than anything to do with the Easylease. Semi-perm release systems are extremely durable, they take an extreme amount of pressure and very very high heat. They can't do anything for chemical reactions though. 
seense
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Problems are gone! I guess my molds needed more coats of Easy Lease during break in time? Anyhow I found the masking tape test to be very useful. Thanks for all suggestions. Smile
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