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No, not really. You should definitely not work at these temperatures. Especially not with high temp resins.
First: they tent to be thicker, wich makes them paste like at low temperatures. This means it is much more likely to trap air inside corners and inside the resin itself.
Secondly: if you use high temp resin you will likely heat the mould up to higher temperatures. This will let the trapped air expand, and ruin your mould surface.
It was you, who wanted to vacuum the mould, because he was fearing he would need to repair it because of trapped air, right? Working at low temperatures is the most reliable way to cause exactly that.
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