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If you are going to clear coat it afterwards, a bit of spray adhesive won't be a problem, as you should sand the surface of you part before painting. For the same reason, you should not waste your time, buffing your mold to the highest gloss. Just keep sure everything is flat. The glossier your mold, the easier the separation from the part, but a final sanding with 2000 and a light polish is already more than enough.
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