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You don't need a better spray gun, you just need to practise using the one you've got. A top quality spray gun makes the difference in the hands of a top quality spray painter, but if you don't have much experience with spray painting then you wouldn't notice the difference between a job laid down with a $50 gun or a $750 gun.
As oekmont suggested, coremat works ok for building thickness. Personally I prefer not to use it in moulds as it isn't as good as a monolithic laminate, but for a one off it will certainly do the job. Alternatively, pieces of timber bonded or glassed to the back of the mould are a common way to form a rigid backing structure. Timber is a good option because it doesn't shrink like composite resins do, so a well designed timber backing structure will ensure your mould remains dimensionally accurate. A mould made with coremat will twist if it doesn't have the geometry to resist, which your roof doesn't. But again, you're doing this for a one off, so coremat is easier and will do the job.
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