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Tooling pre-preg doesnt like Duratec, I have tested that myself and don't recommend trying it.
There is no problem at all with post-curing a mould off the plug, the trick is to do it extremely slowly. If you can do any sort of elevated temp cure on the plug then this definitely helps, even if it is only 40C; 80C is even better. Once off the plug, you need a very controlled ramp rate of 0.1° per minute, with soaks every 10° for at least a couple of hours. Remember that print through is a product of low resin content, so a resin infused CF sheet is very likely to suffer a lot of print through. A wet-lay mould with a surface coat should see less print-through, but you also want to maintain dimensional accuracy, so a slow ramp rate is very important.
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