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24 hours is the minimum time before demould, and it is only enough time if the ambient temperature never drops below 25 degrees. If it gets cooler than 25 in those 24 hours, then it is best to wait 36 or 48 hours before demoulding. To be honest, I prefer to leave ambient cured parts in the bag for a week to reduce the level of fibre print through that occurs. Or do an elevated temperature cure.
As for peel ply removal, that is actually always a difficult task. It depends a lot on the geometry of your components, the consumables on a complex part will be significantly harder to remove than on just a flat sheet. Also if you have pleats or overlaps in the infusion mesh where it becomes multiple layers thick, this can be even more difficult to remove. My advice is to use plastic release film between the peel ply and the infusion mesh (EC's bread wrap is great for this). Then you can generally remove the flow mesh quite easily, which in turn makes it much easier to remove the peel ply. Again, complex geometry makes this more difficult, but it does help.
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