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The XCR would need to be manually applied to fill the pinholes. You then would coat the whole panel in XCR and once cured, flat back the XCR and then polish back to a high gloss. XCR is quite thick so spray application may well be very difficult to master.
As Matt says, finding the cure to the pinholes is the best bet. If your bags are leak tight, then sometimes, keeping the resin feed open a little longer than you normally would - say an extra 30 seconds or so - allows extra resin into the part which ensures all the carbon is FULLY wetted out and maybe fractionally resin rich meaning the chance of pinholes is minimised even further.
Warren Penalver Easy Composites / Carbon Mods - Technical Support Assistant
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