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Generally in silicone moulds, by the time you have sanded the cast resin ready for painting and wiped down with IPA/acetone, there is no problem with paint adhesion. Quite a lot of crafters use silicone moulds for resin casting work where the parts are subsequently painted.
If you did want to go down the PX 60 route, you would probably need a spray on release agent for ease of use.
Warren Penalver Easy Composites / Carbon Mods - Technical Support Assistant
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