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Dentex, I recommended to you, don't experiment. I have made a several MDF CNC machined plugs for autoclave prepreg moulds. There are a coulple ways how to do that efectively. I recomended to you, use only epoxy based coats - post cured, certainly not PUs. If the mould/plug is a single-purpose and hand laminate only, 2K-PS filler is ok. If the plug/mould is a MDF massive block, the tested temperature resistance is 65C, for tooling prepregs enought. Alternatively, instead the tooling prepregs, is possible to use dry carbon cloth + infusion. In both cases, you have to post-cure the mould - out of plug. Very slowly going up to working temperature + 10C min. Remember that the post-curing process can ruin the mould because distorsion and cracks. Depends on mould shape the steel/AL support frame can help, especially for flat large moulds. I have tested the MDF sheet 18mm thick and on 60C starts the distorsion, for massive block 150mm thickness on 80C seems a quite stable. If the CNC available, start thinking about epoxy tooling boards or AL machined moulds. That's the best, high accuracy, high effective way for prepreg moulds.
The oven heater plates or spirals are too massive pieces of steel. It means, has high thermal inertia. It means if the controller switches off on target temperature, in real the temperature goes up uncontrolled by tens of C. The heat is acumulated in the plate. That's the real problem for ON/OFF controller, not so for PID if is right tuned. Better to use the heat resistant wires, for example Kanthal based. Good luck
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