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It sounds like the paint has outgassed through an uneven layer of PVA. PVA is normally ok as it provides a barrier. However if the PVA isn't quite even then that could cause issues. Also sometimes if the resin is a little green it grips the mould harder so would likely rip off a weakly attached paint - polystyrene doesn't offer the best bond.
We tend to recommend avoiding using paint on moulds or patterns for that reason.
I would imagine once those parts are fully cured, the paint will wipe off with acetone.
Warren Penalver Easy Composites / Carbon Mods - Technical Support Assistant
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