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You can certainly aim for the tacky stage if you're looking to use it to help hold your fabric in place, but you can leave it until completely cured to the touch also. It's usually okay to leave it overnight if needs be and it'll still adhere well to the epoxy.
It doesn't apply very well with a brush, but rolling it might give better results. Spraying is usually the best method of application as it's quite thinly formulated, so it might not adhere too well to mould sides if applying by hand
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