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You will find with polyester resins, any surface open to air will cure with a tacky finish and may wrinkle as you have described.
If the wrinkling is on the resin in contact with the mould surface then the possible causes could be moisture in the mould, or over catalyzing the resin leading to high speed curing and heat distortion of the resin.
Warren Penalver Easy Composites / Carbon Mods - Technical Support Assistant
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