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For extensive knowledge on silicones, contact the Wacker distributor, in your case, MC Technics in Vise. I know they have a lot of knowledge, and can provide you with a lot of technical info, very probably also on expansion rate of silicone.
Forget about the intumescent stuff. Once expanded, it does not contract anymore, and it forms a very hard and brittle residue, which is insulating and fire resistant. Great for the purpose of fire protection, but not for cores.
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