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You are correct in thinking there is a limited lifespan with silicone moulds. 20 pulls from the mould is typically about right for a complex shape with a PU or epoxy resins. Some simpler shapes will be easier to demould and last longer as you have found.
What happens is that during the cure process, many resin systems will dry out some of the natural silicone oils in the mould. Over time this will compromise the mould surface and eventually the mould will be too worn to use and/or stick to resin. The effect depends on the resin system - some are more aggressive than others and also the shape. There is an element of mechanical flexing to the wear as well hence why simple shapes which are easy to demould are likely to have a slightly longer mould life than complex shapes needing a lot of twisting and stretching of the rubber.
A technique that works well to improve mould life is to rub some pure silicone oil into the mould after each use to replace lost oils. Also using some of the silicone release sprays helps by protecting the mould surface as well.
Warren Penalver Easy Composites / Carbon Mods - Technical Support Assistant
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