Glasscast 50 not curing fully hard


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ajay_m
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Hi folks
I cast a small tapered pyramid in Glasscast 50 with base dimension 13 X 13mm and top dimension 6 X 6mm, with a total height of approx 65mm. The mould was made from Polycraft GP-3481 condensation silicone. It was cured for 48 hours before use. The mould master pyramid was 3d printed using standard PLA resin, which was then sanded down to create a smooth surface.
I mixed resin and hardener using a precision digital scale with resolution 10mg and confirmed the scale calibration using a reference weight first. I mixed for several minutes to be quite sure of uniformity given the small size of the cast, but made approximately twice as much resin as I required to ensure that I would have a uniform mix for the cast.
The resin was left to cure at approximately 20 degrees for a week. At this point it turned out very nice and bubble-free and was left to cure in air for a further couple of days. However since that point it's never really fully hardened. It feels hard but will slowly deform under pressure. (i.e it will bend slowly if bent by hand). It also can't be properly polished up to the optical finish I require. 

The excess resin, which was mixed in a disposable plastic cup, has however hardened perfectly. This makes me wonder if I have an incompatibility between the resin and the moulding compound, which uses a tin-based catalyst. Should I use an additive silicon product instead, or should I have cast in two smaller pours?. Or should I wash out the mould e.g with isopropyl alcohol or something prior to use?. 
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Warren (Staff)
Warren (Staff)
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The GlassCast range has been tested in condensation and addition cure silicones and both were curing without problem.  We have not tested that specific silicone however, so there could be some kind of issue with that brand. Usually with cure inhibition, it is the surface in contact that does not fully cure so for the whole thing to be soft is a little strange.

It does sound like it has stopped curing at about 95% cured. Is the surface tacky at all?  Typically if there is an imbalance of hardener and resin, or poor mixing you would get a slight tack to the surface.  Very small batches can cause problems in terms of small errors being proportionaly magnified and even things like the corners in a mixing cup which has unmixed resin in can have enough volume to upset the mixing ratio.  Also that size makes it harder to build up heat  which is needed to cure.  So it could be that or a combination of factors having an effect here.

The fact the cup went off ok does lean potentially to an issue with the silicone as a significant factor so something to look at for sure.


Warren Penalver
Easy Composites / Carbon Mods - Technical Support Assistant
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