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Styrofoam and any polystyrene derived foams are sensitive to being dissolved by styrene and the solvents in polyester and vinylester based resin systems, so you need to seal and protect the surface first.
That is where products like styroshield come in. Sandability can be an issue with epoxy resin. However for most cases you could use the epoxy to seal the foam then coat a typical pattern coat primer or similar material on top and work that to get the smooth finish.
Also if you are hoping to reuse the mould, you might want to consider adding a couple layers of woven glass fibre to strengthen the mould further.
Warren Penalver Easy Composites / Carbon Mods - Technical Support Assistant
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