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It's not inflation or anything pneumatic; it's shrinkage of the resin. By demoulding before the resin was filled cured, you had nothing to keep the laminate held in shape, and so the resin shrinkage caused it to curl up. The direction of the curl is dictated by the geometry of the shape, as well as the fibre orientation. Certainly the sun would have made it worse, as the higher temperature would have increased the shrinkage.
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