Hi Michael,
Sorry Paul's not got back to you on this, we have a training course on this week and he takes the course and therefore doesn't get chance to check back in on the forum. I'm sure I can answer your questions....
1. should i put the master into my mdf mould frame before pouring in the silicone or after? Does it matter which method?It doesn't make a huge amount of different. I think the more common practice would be to position the master in place and then pour the
Addition Cure Silicone Rubber around it. Don't forget to secure the master down, I don't think acrylic is lower density that silicone (which would cause it to float) but it's quite close and so not worth risking.
2. i love the look of this art that was made in the 60's by Eva Hesse, actually, this brownish yellow stuff is what originally attracted me, many years ago to resin casting. Do you possibly know what this is exactly, what materials create this color and where I can find this material? It's difficult to say exactly what Eva's pieces are made from but certainly the appearance of them is very similar to the appearance of a cured sample of
GP Laminating Resin. Once cured, the GP resin has that slight translucent brown tint and might be very close without any modification, however if you did want to tweak the colour then our box of 10
Translucent Tinting Pigments includes a 'Burnt Sienna' colour which is a really nice caramel brown colour.
It would also be possible to recreate a colour and appearance like this using a clear resin such as our
Water Clear Polyester Casting Resin or even our
Water Clear Polyurethane Casting Resin (although really this second resin would need degassing to remove air bubbles) and then just tinting them using the tinting pigments I linked to earlier.
3. there are little chips and dings in my master that need to be filled with putty and sanded smooth. what do you recommend for this?
If you're using silicone to make the mould then it won't really stick to anything so you can, effectively, use anything you want to patch-up your master. Polyester bodyfiller might be any option or, if you're careful, you might find that our yellow filleting wax, which can be shaped and smoothed incredibly easily, would be a simple option.
I hope this helps and look forward to seeing your finished pieces 
Best regards, Matt
Matt StathamEasy Composites / Carbon Mods - Technical Sales