Hi ..
Watch as many of the EC tutorials as you have time for... they will tell you a lot..

Take a look at the "car bonnet" vids ... part 1 and 2 deal with "plug" and Mould" making.
Also search Youtube for vids showing mould building and wet-lay of boats, cars and even planes..

When working with Polyester and Vinylester resins, work in a well ventilated area and use a mask... Styrene vapours are very nasty stuff...
And .. No, the Polyester and Vinylester resins you have only require the MEKP/MEPOXE catalyst around 1,5% to 2 % (normally)
(check the datasheets/info for the resins.)
Good luck!
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