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Ok, so - you havent really experienced a release failure here, atleast not a total one. If your release hadn't worked at all, you wouldn't have been able to remove the gelcoat afterwards at all, so the fact you were able to remove the gelcoat and leave a glossy surface tells me the release agent did its job. When you have a release failure, it is absolutely impossible to remove the gelcoat.
So what's happened here is a total adhesion failure between the substrate and the tooling gelcoat, which is somewhat more strange. The fact there was more adhesion between the released surface of the gelcoat and the carbon part than there was between the tooling gelcoat and the reinforcement is concerning. What did you make the mould from and how did you lay it up, what was your process?
You may have had a partial release failure as well, where the release agent worked well enough to not allow the epoxy to bond to the gelcoat but not well enough to allow a very easy removal. But the fact the gelcoat came away from the mould reinforcement means that is what actually failed, and the tension between the epoxy and the gelcoat only aided in pulling the gelcoat off the mould easier.
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