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I agree with Oekmont that pre-preg is not going to be the fastest method for a surfboard. Pre-preg isnt really a fast process, it just CAN be faster if you have really complex geometry. For geometry as simple as a surfboard, throwing all your dry reinforcement into a mould is going to be far less labour intensive than pre-preg.
The CTE of the materials is only going to cause stress when both are rigid - the uncured fiberglass is soft and wont cause any stress. Once it is cured, it will be fully expanded and not cause any stress. As it cools down, the fibreglass will shrink again and self-release. Hence why it is a good idea to have a mould with a low CTE. If your mould has a higher CTE than the material you are curing in it, like carbon pre-pregs in a fibreglass mould. In this case, the materials are fine as they heat up, but then the low CTE material (the carbon) stays the same size while the fibreglass shrinks back down, causing stress.
Theres no need to have your mould Tg so far above your pre-preg cure temperature. To maintain surface finish for as many cycles as possible, it is probably ideal to have a mould Tg of around 135-140. That said, I've got moulds with a Tg of 120 that I frequently use to cure pre-pregs at 120. I'm not aiming for thousands of cycles so it isnt as much of a concern for me, but after 50 or so cycles there is no sign of any mould degradation.
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