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From a shipping persepctive, MEKP is very hazardous. The reason is because it's highly oxidising and so, if combined with a fuel (cardboard for example) will produce a potentially explosive mix. Since most transport packaging for smaller consignments is a cardboard box and combination of cardboard and MEKP is potentially explosive, it's easy to understand why transport regulations on MEKP are so strict. In fact, many ferry companies have a blanket ban on strong oxidisers such as MEKP.
That is why it is hard to ship in large quantities. I'd have to check with our DG team but it's possible that in 20ml containers it would come under 'Excepted Quantity' for IMDG/ADR which would explain why these small containers are more readily available.
Warren Penalver Easy Composites / Carbon Mods - Technical Support Assistant
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