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To get the part sitting flat a would suggest bonding it with hot-melt glue down to a sturdy setup-board. A great material for the setup board is 'conti-board' this is the white plastic coated chipboard stuff that the unside of your kitchen cupboards will be made from, you should be able to get some easily from your local hardware store or timber merchant. This board should provide a nice flat platform to glue it down to.
If you are looking to make any changes to the donor part its easy enough normally; just tweak the shape using car body filler and fibre glass until you have got it to the shape that you want, then you can either release agent it up and pull your moulds straight from the filler and get the final polish on the mould, or paint the thing in 2-pack paint and polish to a full gloss so your moudl pulls off ready to go.
There's nothing special about the mould or process if you intend on painting it with a clear-coat, the part will just need flatting out with a 400-600 grit paper before shooting the paint to ensure that the clear will bond perfectly.
I look forward to seeing how you get on with this one.
Paul Statham Easy Composites / Carbon Mods - Technical
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