Hi everyone, this post is an information sharing exercise rather than a question. I've been asked for details about my experience with using silicone for moulds.
I have used two types of silicone so far and they have both been "Wacker Chemie" products. Both were platinum cured and one was firmer than the other. Model numbers were 4644 and 4670.
It's a part A plus part B scenario just like resin but a lot thicker. I think you can get one part stuff but it's not as good. I just want to clarify that those two model numbers weren't the part A and part B numbers. Each of those models come with their own part A and part B.
It takes about 24 hours to cure and when it does, it's just like a block of rubber. It has excellent detail reproduction too. Even the logo from the back of my iPhone could be seen in the silicone and you can't even feel the logo on the phone.
It is very strong stuff and extremely resilient to epoxy. I've used my moulds about 20 times so far without any degradation.
It is very heat resistant, even to the point where you can cast "low melt alloys" in it. I'm about to find out how much thermal expansion it has too so watch this space.
It is fairly expensive and so you wouldn't want to make anything too big with it. Just google RTV2 for a local supplier and prices.
It doesn't need any release agent. That's one of my favourite things about it. In the same breath though, you can't really stick wet cloth to it and so your product really needs to be made with one small piece of carbon. Or all the bits need gravity to keep them in place.
Here's a pic of my mould but please don't laugh at all the air bubbles, I don't have access to a vacuum chamber...

Most of those air bubbles have actually floated away from the good surface by the way. When I say most I really mean most, there might only be a handful still touching the good side. Resin does get into them but when you demould your carbon those resin bubbles just pick off as if they were never there.
Here is a pic of what came out of the mould... This pic, by the way, is of the cover I just made with the homemade prepreg. That's for those of you following the "kitchen oven" thread...

Silicone seems to work for me as I'm working with small flat shapes but it won't work for everyone.
Lastly, I would like to stress that I'm NOT an expert and everything you just read might be rubbish.