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It is resin shrinkage. Areas of excess resin shrink more. Due to the reasons Warren explained, at the edges of a core with an unchamfered edge, you get bridging. That bridging creates a void that gets filled with resin. The resin then shrinks ever so slightly more than the resin around it. After demoulding, the resin on the surface is no longer supported by the mould surface, so that shrinkage creates a distortion.
That's why it is often the case that immediately after demoulding a part, it can appear perfect. Then if the part hasn't been post cured (and sometimes even if it has), in the hours and days afterwards as the resin continues to fully cure, you can watch the surface slowly distort and any surface print become more and more obvious.
With epoxy, thicker skins on either side of the core are sufficient to block that tiny degree of print through. With vinyl ester and polyester the shrinkage is so much higher that I have seen cores and backing structures print through 25mm+ thick skins to distort the gelcoat enough that you can easily feel it by hand.
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