Mysterious color changing with natural fibres


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Marco Todeschini
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Hello everybody I'm experimenting with resin infusion for only a year, so maybe it's just a beginner question but I'm really stucked with it.
I'm making composites with jute+epoxy resin and I can't find the logic under the changing of color of the finished part: sometimes I get light colored part with clearly visible and contrasted jute texture (which I like), sometimes jute seems deeply soaked,and looks darker and uglier. In these bad cases it's also more likely to have problems like bubbles or voids.
I did some tests trying to understand why it happens, but without results.
Jute and resin (supersap biobased epoxy) are always the same, temperature and humidity don't change too much, mold is the same.

The only things changing is the vacuum bag: sometimes a standard bag, sometimes a custom self-made silicone bag (made with Smooth-on EX-Brush silicone), but I have color changes even using the same bag type.
Just to give an example: with a silicone vacuum bag I have a good result, with a identical silicone bag I have the "dark effect".
Again: with a standard vacuum bag I have a good result, the next time I change a bit the layout of flow mesh and I have the "dark effect".

I noted that if I do a hand-layup test it always comes light-colored (good), and this gave me the idea that the dark effect could be caused by the to high vacuum level: I imagined that in a perfectly sealed mold under a full vacuum the resin struggled to move, and was forced to pass INSIDE the jute fiber, wetting it more deeply and thus darkening it more (this would go along with my theory that the first silicone bag I made worked better, maybe because having less experience I did not make it perfectly sealing).
So I bought a SMC Vacuum Regulator, nothing seemed to change. Also, EasyComposite support informed me that it is not intended for resin infusion.

Has anyone ever come across such a problem?
I really can't find the cause, I'm sure I'm really missing something important!

Thank you very much,
Marco

I post a pic of the different results I get

The mold+silicone bags I'm using. Even if the seem identical, someone gives good results, someone gives the dark effect

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Marco Todeschini
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Hanaldo - 12/16/2020 1:11:36 AM
Marco Todeschini - 12/15/2020 9:31:35 AM
Hanaldo I think it makes sense, even if the channel is microscopic: I'm much more experienced in woodworking than in composites and I can tell you that there is a drastic difference in color between woods finished with finishes that soak the grain in depth (like oil based ones) and woods finished with finishes that penetrate less deep. In both cases "deep" and "less deep" refear to microscopic measures. I think it could work in a similar way.

Anyway: new day, new experiment, new failure Wink : yestarday I tried to come back to the good old disposable vaccum bag (the last experiments were all done with silicone bags). The infusion came very badly, probably a leak at the entrance of the resin, BUT something interesting happened: all around the part damaged by the bubbles the color is light. 
In that area a bridge was formed, where the air from the leak was then collected, which perhaps compressed the laminate less (returning to the thesis of less compression = lighter color).
I absolutely have to do a test by adjusting the vacuum level:
1) Do you have any advice on the lowest (but working) vacuum level to keep?
2) In my limitate experience I've always heard that infusion needs the absolute absence of leaks to work. The vacuum regulator works by entering a small controlled  leak, right? How do the 2 things get along?




Sure, but composites lamination is very different to coating wood, even if the natural fibres have similarities.

What we are really suggesting here is that the fibres do not wet out properly when hand laminating. That has massive consequences on the finished laminate, not just colour difference. Do you notice any differences otherwise; does it feel a bit dry to cut, is it a bit lightweight, is it flimsier than the infused panels?

I think it is important to understand that hand lamination, unless done very poorly, doesn't effect how wet out the fibres are. A hand lamination resin will have very good fibre penetration, and unless you go very lean and don't apply enough resin then it will wet out the fibres. The only difference should be in void content and fibre consolidation, a hand laminated panel will include significantly more air in the layup than an infused panel and the fibres should be pressed tighter together with less space for resin (and voids) between the fibres. The actual centre of the fibre itself, if that can be wet out when infused then it should also be wet out when wet-laid.

I feel the fibre compaction is the more likely explanation. Theoretically the infused laminates should have a higher density per cubic mm than the hand laid laminates. Less space for resin and voids would also mean less space for light refraction I would think. 

The caveat - we are still kind of ignoring the fact we have both had lighter coloured results from infusion. Perhaps hand laminated seems to always result in a light coloured part, but infused does not always result in a dark coloured part. So what changes between those samples? If I had a bit more time I would do some experiments myself. Maybe on the weekend I will get a chance.

Thank you Hanaldo, you clarified my ideas about hand lamination quite a lot. Actually I can't find any big structural differences between dark and light laminates, and as you say, any resin lack should have significant negative effects...
I tried to make an infusion to 0.6 vacuum: it was a failure because the resin was too slow and started curing during it, but at least it seems to show that
lower vacuum level>>less compression of the fibres>>lighter color. (you can see it in the center).

I would like to ask if your infusions with different darkness were made with the same vacuum level.
I'm afraid that, even with the same vacuum level, this problem can occur just for a different arrangment of flow mesh, peelply, etc ... that makes the bag more prone to push against the jute. (this would explain the reason of the color changes BEFORE I bought the vacuum regulator)
For this reason I'd like to understand the logic and then apply it to a reusable silicone vacuum bag.
(about silicone bags, I will try to make one with a larger offset and a higher shore value, so that it is more difficult to it to push against the jute)

GO

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