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I dont find 100g THAT much more conformable than 225g, so I would just use the 225g. Sharp 90 degree corners are the limit for 225, and 100g cant manage them either, so it's always best to find another solution for that.
That said, I have laminated moulds after 48 hours without issue. I wouldn't do it for a critical mould that you are wanting to use many times, especially if it is sizable, but for a small mould that you can easily make again later and only intend to get one part out of, it tends to work out fine.
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