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We've had mid-30 degree ambients in Perth lately, so it wouldn't be impossible to PVA that mould inside 30 minutes. If the PVA was touch dry when you moved ahead then it wouldn't be a problem. Realistically, that issue would present itself in a different way, it wouldn't cause seperation issues. But on the topic of PVA, are you spraying or brushing it? I can't remember if you mentioned in your first post. The results will be infinitely better if you are spraying it, so if you don't have spray equipment I would recommend grabbing a Preval sprayer from Supercheap and applying it that way.
To me, it sounds like the PVA isn't a complete film on the surface and you are mostly applying the epoxy to the waxed mould surface? In which case, a low viscosity resin is going to seperate and pool very easily. I would suggest using a thicker laminating epoxy, and you could try wetting out your carbon on a sheet of plastic before you apply it to the mould. Use a squeegee to squeeze out excess resin, and then just take your time making sure it all conforms to the mould surface. You will likely still get a few voids because this isn't an easy shape to do without vacuum, but it isn't hard so hard to fix compared to what you have now.
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