CS25 Silicone rubber turned into an adhesive!!!!?


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TURK
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Hi guys,

Thought I would post an update on the Quad Headlight Project, but more importantly how I got on with my replacement CS25 Silicone rubber  ( thanks Warren ). I think it's only fair that I should share my results using CS25 silicone rubber as everyone has been so helpful, and are probably wanting to know themselves how things turned out. I'm no expert guys, many of you would probably have worked that one out yourselves!

So my recommendation would be ( and that's purely my opinion ), what I concluded was the mould release agent I used wasn't compatible with the silicone. Probably totally wrong!
So, on this attempt I used the 'Mann' Ease Release 200 mould release agent that comes in aerosol can.

 This was what I was left with after my disastrous first attempt,  the silicone mould was useless and my plug was damaged, the other one was even worst! >>


First thing I had to do was to repair my plugs, as they're basically layer upon layer of Pattern-Coat Primer resin, I had to sand-back most of the previous layers, and then begin to re-apply really thick layers of PcP in the broken areas ( a bit like using Polyester filler ) >>


Because I the headlight design,  these will actually be for the headlight covers I intend to use,  there's a line ( that I call the 'swagline' )  all the way round the plug,  it kind of makes working with the plug awkward,  simple things like sanding become quite awkward,  but it's needed for making the part structurally sound and adds definition to the shape.  So in almost every step of the process I have to add blue painters tape to either protect the swagline or give it form  >>


Then the sanding begins ...................  If you hate sanding stuff,  mould making isn't for you!  >>


Lots more sanding later .....................  the 'swagline' is well established,  and it's just a case of working the plug till you regain the initial shape back  >>


A few more days of sanding,  all the while checking your dimensions,  you're almost back to where your were the previous month  >>


Now it's just a case of working through the sandpapers  >>


After the 1200 grit wet & dry things are beginning to look up.  It never ceases to amaze me just how good you can get the Pattern-Coat Primer to look.  It's like a glass-like finish it's that smooth.  And that's without using the 'Pattern-Coat High-Gloss' finish >>


Then it's onto the polishing stage,  then a few coats of wax.  I got the things so buffed up that I could actually read the wattage of the over-head light reflected in the plugs!  >>


Now the plugs are fully repaired,  buffed up to a high sheen it's time to install them into my mould set-up boxes.  As I need to reduce the hight of the plugs by 30mm ( that will become my 'tooling plugs' for vacuum forming my parts ),  I simply glued the batons in place and filled the voids with 'NewPlast' plasticine  >>


As the bottom of my mould set-up box will become the top on my actual completed silicone mould,  there's no reason to make a pigs ear of it.  The edges must be crisp and sharp >>


I'm not going to go through the entire CS25 silicone preparation and pour,  as that's already been covered  on the first page,  as I've already mentioned, the only thing that I did differently was to use the 'Mann' aerosol release agent.  De-moulding time - Already things didn't look good!!!  the sides of the mould box were well stuck ..............  it took quite a lot of persuading to release the sides,  no damaged was caused to either the silicone mould or the set-up boxes themselves ( I will need those again in the next stage ) >>


In the end,  everything worked-out just fine  BigGrin  well pleased with that >>


The quality of the silicone finish is superb and the definition is bang on.  And as intended ( hoped ) the swagline is nice crisp and sharp >>


The next stage will be to cast 'Vac-Cast Epoxy Resin' into these.  But a solid block of vac-cast resin isn't what I want or need.  For a proper vacuum forming tooloing plug,  the tooling plugs have to be hollow.  I'm hoping to use plasticine,  about 20mm thick ( rolled-out with a pin-roller ) to 'line' the bottom of this silicone mould.

Does anybody see any issues with that method?
I'll be using cling-film as a barrier so the plasticine doesn't stick to the silicone.

My other question,  and really my reason for posting this article,  PLASTICINE ..................  can I put plasticine in a microwave oven to soften it?  I've made a 'heat-box' to soften the plasticine, as I need it to be malleable so I call role it into flat slabs.,  but it takes all day just to soften it just a little!  Microwave method any good?

Anybody tried this method?  I'd like to hear from you if you've tried this.


And just to finish off ...................  The only issue I had ( the silicone sticking to the sides of the mould set-up box ),  was due to the fact that the 'Melamine' wasn't actually Melamine at all,  but just a cheap finish to make it look like Melamine!  When I looked closely at it and picked at it with my finger nail,  I realised it was a type of compressed cardboard made to look like Melamine!  The junk they make now days,  nothing' real anymore!



TURK
T4 Concepts

Sparky2305
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Wow Turk 

 Busy Busy Busy good stuff!, I hope to retire to france myself one day!!

Sparky

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Sparky2305 - 10/31/2018 1:31:59 PM
Wow Turk, are these the quad headlamps for the T4? I remember the thread in the T4 forum from years ago, is it still running?

Thanks

Hi Sparky,

Yeah,  same ones! ..............  this project has been ongoing for  while now as you say.  I emigrated to France in the meantime as I used to be in the UK as you know,  I built a proper workshop, a design studio and bought a shyte load of tools and machines!  And since arriving in France I started the whole project again,  I discovered a far better way of fabricating my quad headlight concept ( amazing what can be achieved when you have the proper tools! ).

I'm not just making one type though Sparky,  I believe in giving customers the choice,  so I'm making the 'Classic' range,  the 'Performance' range, and the 'Premium' range.  And I'm also designing the quad headlights for the long nose T4 ..............  so basically,  I'm having to make at least 7 different options!  Wink  >>


Here's a set of the 'Performance' range on my T4 Lulu!  BigGrin  >>


I'm also making the Hella Bi-Halogen range  >>


All that remains to do are the headlight covers ......................  and as you can see from this thread,  I'm having difficulties!



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T4 Concepts



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Hanaldo - 10/31/2018 11:35:28 AM
I dont mean completely uncured, I mean somewhat 'green'. Its a similar situation to demoulding epoxy too early. It can feel rock hard, it's even stiff and solid and not sticky at all - but if you demould epoxy too early, it will grip the mould like all hell, and cam destroy moulds. Very common with 'slow' hardeners where people dont give it as long as it actually needs, so even after 24 hours it is still not properly cured and hasnt reached the appropriate barcol hardness to release.

Silicones are similar. If you try to demould too early, theres a stage of the cure where it behaves as if it is totally bonded - even though it isnt.

Oh, I see ..............  well,  thanks for that information Hanaldo.  Yeah,  the stuck silicone on the surface of the plug,  where it hasn't torn the Pattern-Coat Primer off,  is rock hard!
It's not sticky though,  just rough and hard.  It will take some sanding down but I'm pretty sure I can save my plugs.

D'you think that I should leave the silicone cure longer then?  The data sheet says 24 hours.  My workshop is constantly at 20°C +  ( never over 25°C ),  I have no option,  I have to try this again ................  making mistakes is the way we learn and become experts,  it sure is an expensive learning curve though!


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So as i read it , you did NOT use the spray release this time? If thats the case it points towards solvents from the release coat, although if you have left it more than an hour between coating and pouring silicone then they should all be gone. Unless perhaps some of the solvents had soaked slightly into the Pattern Coat surface and it outgassed slightly during the silicone cure.

The solvents from the EasyLease release agent would of been well dry Warren,  as it was at least a couple hours before I was ready with the silicone pour.  As far as the EasyLease release agent 'soaking' into the Pattern-Coat Primer on the plugs,  that wouldn't be a good thing at all,  as the plugs were made a few months ago so they would of been cured an awful long time ago.

Of course,  I'm just guessing at what has transpired.  But sometimes just mulling things over, a solution is found.

I was intending in continuing with casting the 'Vac-Cast Epoxy Resin' into these moulds.  But now the issue with the residue on the surface of the silicone,  I doubt that anything I try will work.  I'll more than likely ruin my Vac-Cast tooling plugs as well.   I'll have to start again from scratch!   this will undoubtedly add a few weeks to my ongoing project,  but it's for a good cause.

* Just received your email Warren ...............  Many many thanks,  I'll keep you informed mate  Smile



TURK

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Wow Turk, are these the quad headlamps for the T4? I remember the thread in the T4 forum from years ago, is it still running?

Thanks
Hanaldo
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I dont mean completely uncured, I mean somewhat 'green'. Its a similar situation to demoulding epoxy too early. It can feel rock hard, it's even stiff and solid and not sticky at all - but if you demould epoxy too early, it will grip the mould like all hell, and cam destroy moulds. Very common with 'slow' hardeners where people dont give it as long as it actually needs, so even after 24 hours it is still not properly cured and hasnt reached the appropriate barcol hardness to release.

Silicones are similar. If you try to demould too early, theres a stage of the cure where it behaves as if it is totally bonded - even though it isnt.
Warren (Staff)
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It is strange that the residue is appearing now.  That would imply there is some reaction still going on now (or recently) many days after the initial cure. -  which would point to something leeching off the silicone surface.

So as i read it , you did NOT use the spray release this time?  If thats the case  it points towards solvents from the release coat, although if you have left it more than an hour  between coating and pouring silicone then they should all be gone.  Unless perhaps some of the solvents had soaked slightly into the  Pattern Coat surface and it outgassed slightly during the silicone cure.


Warren Penalver
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Hanaldo - 10/31/2018 4:14:38 AM

My gut feeling is that this is undercured silicone as Warren suggested. This is the only time I've ever had silicone 'bond' to a surface that wasnt either porous, glass, or silicone.

Pretty sure it's nothing to do with uncured silicone Hanaldo .......................  Look at the picture at the top of the thread,  the one that shows my plug.  That silicone is solid,  and stuck to the primer,  I'd even have a tough job sanding it off.  I had to literally tear the silicone mould off my plug.  According to the data sheet of the product,  a full cure is achievable in 24 hours ....... it was more like 26 hours before I began to de-mould.  So it's not that,  I'm beginning to think it was something to do with the release agent reacting with the silicone.  And it's probably that that's causing this residue to build up on the surface of the silicone mould now.


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Warren (Staff) - 10/30/2018 1:36:21 PM
Turk, when you made the previous set of moulds a while back by the same method, was that using a release agent  too?


Hi guys,

It's interesting to hear that Fasta encountered issues using a release agent,  which got me thinking ( and this also relates to your question Warren )  ...................  Did I actually do something different last time!?  So I went through my notes from my previous job.  I also take pictures of my projects as I post them on other forums,  so I went through all my pictures that I took on the day.

This photo is of the headlight mounting bracket that I was working on.  The plug that can be seen in the background,  is made of High Density PU foam and finished off with Pattern-Coat Primer ( same as these headlight covers plugs )  the silicone is the same CS25.  As you can see,  the silicone mould turned out perfect,  and no issue de-moulding,  took less than ten minutes to de-mould.  >>



But there was a difference! ..................  When I 'prepared' my headlight bracket plugs ( the one in the image above ),  I applied a few coats of 'EasyLease' release agent as is usually instructed in the data sheets.  That I usually do a few hours prior,  or even the day before.  But last time just before pouring the silicone into the mould setup box,  I sprayed my plug again with some 'Mann Ease Release 200' mould release agent.  And that' usually done before I weigh and mix my silicone so it's got ample time to dry.

The main difference is the use of this 'Mann Ease Release 200'  mould release agent,  it clearly states on the aerosol can 'For use with Silicones, Urethanes & Resins'.  Having read that,  I went back to the 'EC Easy-Lease' release agent data sheet,  and it states  ......
"With the exception of silicone rubber and materials subject to solvent attack Easy‐Lease™ Chemical Release Agent will work with many combinations of materials, however, we would always advise testing any new resin/mould material combination on a small sample before committing to a full moulding'"

Strange wording!  It's a warning of sorts ( I think! ),  like,  you could use 'EasyLease' release agent but not recommended when using silicones.

So,  basically what I did last time was to spray a release agent ( Mann 200 ) on top of another release agent,  which was more compatible as it's specifically formulated for use with silicone rubbers.  I may be totally chaps  Ermm  and I don't know what I'm talking about!

My previous moulds ( headlight mounting brackets in the photo above )  are still great a year later.  Notice how white and blemish free they are ..........................

Now compare them to the moulds of my headlight covers that I made last week.  Awful patchy off grey almost black the silicone is,  and the pitted surface is.  Blink  >>



Now it seems that the silicone moulds ( both of them ) have secreted a slight film ( or residue ) on the surface!?  You can just see where I've run my finger tip on it.  What is that?  that never happened last time.


TURK


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