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Yeh you haven't got much choice, there's no real short cuts. If you can't use surface coats that resist the solvents in the gelcoat and heat from the curing of the mould, then you need something that forms a barrier between the two - that's PVA, or wrapping the object in release film or release tape. Those two options will prove much more difficult than PVA.
That said, PVA can be sprayed in such a way that it can give you a decent surface finish - certainly as good as a primer finish anyway. You will still need to do a bit of denibbing and polishing of your mould to get a truly Class A finish, but you would have needed to do the same off the primer surface as well.
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