+xHi Maggie,
Thanks for the picture. You will be pleased to know you haven't done anything wrong per se. What has happened is the moulds have worn out from all the casts you have taken.
Silicone does not last forever when casting from. Depending on the conditions, type of resin, complexity of the mould/part etc the mould will have a lifespan. Certain resins will wear the mould out quicker - PU being one of them. It tends to dry the natural oils out of the silicone which degrades the surface of the mould and it tends to stick then rip off in chunks. 15-20 pulls is typically what you would expect with more aggresive resins.
You can prolong the life of the moulds by a few pulls by wiping the mould after each pull with pure silicone oil to help restore the natural oils lost.
Obviously you will need to remake the mould, so i would use one of the good casts as a "master" pattern for making future moulds from if you plan to make a lot of these in the future.
oh, thanks Warren! Good to hear that. Happy they lasted a few more pulls then

Yes, I'll use one of the previous casts to remake it! Cheers!